Table 5. Molecular weight distributions of the precipitates (EOL) obtained by organosolv pretreatment of Liriodendron tulipifera at different temperatures

Temp. (°C) MWL 120 130 140 150 160 170 180
Mw (daltons) 10,250 ± 52 5,050 ± 4 5,712 ± 56 6,780 ± 66 6,163 ± 84 4,356 ± 42 2,475 ± 24 1,953 ± 38
Mn (daltons) 4,384 ± 27 2,933 ± 30 2,945 ± 41 2,967 ± 41 2,783 ± 34 1,935 ± 27 1,476 ± 21 1,287 ± 35
Polydispersity (Mw / Mn) 2.34 ± 0.00 1.72 ± 0.02 1.94 ± 0.01 2.29 ± 0.01 2.21 ± 0.00 2.25 ± 0.01 1.68 ± 0.01 1.52 ± 0.01
EOL: ethanol organosolv lignin, MWL: milled wood lignin, Mw: weight-average molecular weight, Mn: number-average molecular weight.